第一作者:Xingxing Liu 共同一作:Qing Zhu 通訊作者:Liqun Jin(金利群), Chao Liu(劉超) 通訊單位:Zhejiang University of Technology;Lanzhou Institute of Chemical Physics DOI:10.1002/anie.201913388 引言 結果可知,該反應對于反應中心的構型具有專一性,反應位點的手性得到保持。利用該特點,可以對一些需要保持手性的化合物進行立體專一的轉化。 劉超,博士研究生,碩士生導師,“特聘人才計劃”研究員 電話:18942912425 郵件:chaoliu@licp.cas.cn 地址:江蘇省蘇州市吳中區(qū)金雞湖大道99號 郵編:215123 簡歷: 04/2015-至今:中科院蘭州化學物理研究所開始獨立研究工作,特聘“人才計劃”研究員 07/2012-03/2015:武漢大學化學與分子科學學院,師資博士后 09/2007-06/2012:武漢大學化學與分子科學學院,博士研究生(導師:雷愛文教授) 10/2008-10/2009:英國杜倫大學化學學院,訪問博士生(導師:Todd B. Marder教授) 09/2003-07/2007:武漢大學化學與分子科學學院,大學本科 研究方向: 羰基化學、有機硼化學、均相催化以及低碳烴化學 招生專業(yè): 有機化學專業(yè)的碩士、博士研究生,博士后以及職工 獲獎及榮譽: 12/2017:高等學??茖W研究優(yōu)秀成果一等獎(排名第三) 08/2017:中國催化新秀獎 02/2017:入選2016-2018中國化學會“青年人才托舉工程” 03/2014:湖北省優(yōu)秀博士學位論文獎 06/2012:Eli Lilly Asia Outstanding Graduate Thesis Award,一等獎 05/2012:首屆武漢大學研究生學術創(chuàng)新特等獎 05/2012:武漢大學2012屆優(yōu)秀畢業(yè)研究生 05/2012:武漢大學2012年十大學術之星稱號 04/2012:武漢大學2011年度十大珞珈風云學子 08/2011:第七屆中國青少年科技創(chuàng)新獎 07/2011:國際IUPAC金屬有機化學及其導向的有機合成反應會議(OMCOS16)最佳海報獎 07/2007:湖北省優(yōu)秀學士學位論文一等獎 代表性論著: 部分獨立工作發(fā)表論文 2018 32) Sun, W.; Wang, L.; Xia, C.*; Liu, C.* Dual Functionalization of α-Monoboryl Carbanion via A Deoxygenative Enolization with Carboxylic Acids, Angew. Chem., Int. Ed. 2018, 10.1002/anie.201801679. 31) Wang, L.; Sun, W.; Liu, C.* Recent Advances of Homogeneous Carbonylation using CO2 as CO Surrogate, Chin. J. Chem. 2018, 10.1002/cjoc.201700746 (Invited Review). 2017 30) Wang, L.; Zhang, T.; Sun, W.; He, Z.; Xia, C.; Lan, Y.*; Liu, C.* C-O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones, J. Am. Chem. Soc. 2017, 139, 5257-5264. 29) Kuan, S. H. C.; Sun, W.; Wang L.; Xia C.; Tay, M. G.; Liu, C.* Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines, Adv. Synth. Catal. 2017, 359, 3484-3489. 2016 28) Zhu, Q.; Wang, L.; Xia, C.; Liu, C.* Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO2, Chin. J. Org. Chem. 2016, 36, 2813-2821 (Invited Review). 部分獨立工作前發(fā)表論文 2015 27) Liu, C.; Yuan, J.; Gao, M.; Tang, S.; Li, W.; Shi, R.; Lei, A.* Oxidative Coupling between Two Hydrocarbons: An Update of Recent C-H Functionalizations, Chem. Rev. 2015, 115, 12138-12204. 26) Song, J.*; Wei, F.; Sun, W.; Li, K.; Tian, Y.; Liu, C.*; Li, Y.; Xie, L. Synthesis of Fluoren-9-ones and Ladder-Type Oligo-p-phenylene Cores via Pd-Catalyzed Carbonylative Multiple C–C Bond Formation, Org. Lett. 2015, 17, 2106-2109. 25) Qi, X.; Zhang, H.; Shao, A.; Zhu, L.; Xu, T.; Gao, M.*; Liu, C.*; Lan, Y.* Silver Migration Facilitates Isocyanide-Alkyne [3 + 2] Cycloaddition Reactions: Combined Experimental and Theoretical Study, ACS Catal. 2015, 5, 6640-6647. 24) Qi, X.; Li, Y.; Zhang, G.; Li, Y.; Lei, A.*; Liu, C.*; Lan, Y.* Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study, Dalton Trans. 2015, 44, 11165-11171. 23) Yuan, J.; Wang, J.; Zhang, G.; Liu, C.*; Qi, X.; Lan, Y.*; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A.* Bimetallic Zinc Complex - Active Species in Coupling of Terminal Alkynes with Aldehydes via Nucleophilic Addition/Oppenauer Oxidation, Chem. Commun. 2015, 51, 576-579. 22) Yuan, J.; Liu, C.*; Lei, A.* Construction of N-containing heterocycles via oxidative intramolecular N-H/X-H coupling, Chem. Commun. 2015, 51, 1394-1409. 21) Liu, J.; Zhang, H.; Yi, H.; Liu, C.*; Lei, A.* A facile access for the C-N bond formation by transition metal-free oxidative coupling of benzylic C-H bonds and amides, Sci. China Chem. 2015, 58, 1323-1328. 2014 20) Wang, L.; Wang, Y.; Liu, C.*; Lei, A.* CO/C-H as the Acylative Reagent: A Palladium-Catalyzed Aerobic Oxidative Carbonylative Esterfication of Alcohols. Angew. Chem., Int. Ed. 2014, 53, 5657-5661. 19) Zhang, G.; Yi, H.; Chen, H.; Bian, C.; Liu, C.*; Lei, A.* Trisulfur Radical Anion as the Key Intermediate for the Synthesis of Thiophene via the Interaction between Elemental Sulfur and NaOtBu, Org. Lett. 2014, 16, 6156-6159. 18) Liu, D.; Tang, S.; Yi, H.; Liu, C.*; Qi, X.; Lan, Y.*; Lei, A.* Carbon-Centered Radical Addition to O=C of Amides or Esters as a Route to C-O Bond Formations. Chem.--Eur. J. 2014, 20, 15605-15610. 17) Song, J.*; Wei, F.; Sun, W.; Cao, X.; Liu, C.*; Xie, L.*; Huang, W. Highly efficient C-C cross-coupling for installing thiophene rings into p-conjugated systems, Org. Chem. Front. 2014, 1, 817-820. 16) Liu, C.; Liu, D.; Lei, A.* Recent Advance of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings, Acc. Chem. Res. 2014, 47, 3459-3470. 15) Liu, D.#; Liu, C.#; Li, H.; Lei, A.* Copper-Catalyzed Oxidative C-H/C-H Coupling between Olefins and Simple Ethers, Chem. Commun. 2014, 50, 3623-3626. (#Equal contribution). 14) Meng, L.#; Liu, C.#; Zhang, W.; Zhou, C.; Lei, A.* Palladium catalysed β-selective oxidative Heck reaction of an electron-rich olefin, Chem. Commun. 2014, 50, 1110-1112 (#Equal conibution). 13) Liu, D.#; Liu, C.#; Lei, A.* Nickel-catalyzed oxidative cross-coupling of arylboronic acids with olefins, Pure Appl. Chem. 2014, 86, 321-328 (#Equal contribution). 2013 12) Liu, C.; Liu, D.; Zhang, W.; Zhou, L.; Lei, A.* Nickel-Catalyzed Aromatic C–H Alkylation with Secondary or Tertiary Alkyl–Bromine Bonds for the Construction of Indolones, Org. Lett. 2013, 15, 6166-6169. 11) Liu, C.#; Tang, S.#; Lei, A.* Oxidant controlled Pd-catalysed selective oxidation of primary alcohols, Chem. Commun. 2013, 49, 1324-1326 (#Equal contribution). 10) Wang, J.#; Liu, C.#; Yuan, J.; Lei, A.* Copper-Catalyzed Oxidative Coupling of Alkenes with Aldehydes: Direct Access to α,β-Unsaturated Ketones, Angew. Chem., Int. Ed. 2013, 52, 2256-2259 (#Equal contribution). 9) Liu, D.#; Liu, C.#; Li, H.; Lei, A.* Direct Funtionalization of Tetrahydrofuran and 1,4-Dioxane: A Nickel-Catalyzed Oxidative Csp3-H Arylation, Angew. Chem., Int. Ed. 2013, 52, 4453-4456. (#Equal contribution). 8) Tang, S.#; Liu, C.#; Lei, A.* Nickel-Catalysed Novel β, γ-Unsaturated Nitrile Synthesis, Chem. Commun. 2013, 49, 2442-2444. (#Equal contribution). 7) Wang, L.#; Liu, C.#; Bai, R.; Pan, Y.; Lei, A.* Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides, Chem. Commun. 2013, 49, 7923-7925 (#Equal contribution). 6) Wang, J.#; Liu, C.#; Yuan, J.; Lei, A.* Transition-metal-free aerobic oxidation of primary alcohols to carboxylic acids, New J. Chem. 2013, 37, 1700-1703 (#Equal contribution). 2012 5) Liu, C.; Tang, S.; Zheng, L.; Liu, D.; Zhang, H.; Lei, A.* Covalently Bound Benzyl Ligand Promotes Selective Palladium-Catalyzed Oxidative Esterification of Aldehydes with Alcohols, Angew. Chem., Int. Ed. 2012, 51, 5662-5666. 4) Liu, C.; Tang, S.; Liu, D.; Yuan, J.; Zheng, L.; Meng, L.; Lei, A.* Nickel-Catalyzed Heck-Type Alkenylation of Secondary and Tertiary alpha-Carbonyl Alkyl Bromides, Angew. Chem., Int. Ed. 2012, 51, 3638-3641. 2011 3) Liu, C.; Zhang, H.; Shi, W.; Lei, A.* Bond formations between two nucleophiles: Transition metal catalyzed oxidative cross-coupling reactions, Chem. Rev. 2011, 111, 1780-1824. 2) Liu, C.; Deng, Y.; Wang, J.; Yang, Y.; Tang, S.; Lei, A.* Palladium-Catalyzed C-C Bond Formation To Construct 1,4-Diketones under Mild Conditions, Angew. Chem., Int. Ed. 2011, 50, 7337-7341. 1) Liu, C.; Wang, J.; Meng, L.; Deng, Y.; Li, Y.; Lei, A.* Palladium-catalyzed aerobic oxidative direct esterification of alcohols, Angew. Chem., Int. Ed. 2011, 50, 5144-5148. 承擔科研項目情況: 1 中國化學會“青年人才托舉工程”項目,2016-2018,45萬元 2 甲烷均相催化轉化新技術研究,國家自然科學基金重大研究計劃培育項目,2018-2020,75萬元 3 雙核過渡金屬催化體系的創(chuàng)制及其在CO2催化轉化中的應用研究,國家自然科學基金面上項目,2017-2020,65萬元 4 過渡金屬催化α官能化烷基自由基參與的環(huán)化反應研究 國家自然科學基金青年基金 2014.01-2016.12, 25萬元 |
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